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71.
本文研究了一种多变量在线测录仪,可用其在定向运转和反复正反变向运转的摩擦学试验中连续测量和记录试样的角速度、方位角、转数和摩擦距离等多个旋转变量的瞬时值,并且通过时间变量的关系,还可以清晰地显示出它们的变化过程和相互关系,基本能够描绘出试样在整个摩擦试验过程中的旋转动态。文章指出,利用这种测录仪还可得出一些间接的信息,如摩擦副的相对滑动量和试验过程中试样摩擦力的变化等。该仪器具有一机多用、所占空间 相似文献
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Dr. Denis A. Malyshev Prof. Floyd E. Romesberg 《Angewandte Chemie (International ed. in English)》2015,54(41):11930-11944
All biological information, since the last common ancestor of all life on Earth, has been encoded by a genetic alphabet consisting of only four nucleotides that form two base pairs. Long‐standing efforts to develop two synthetic nucleotides that form a third, unnatural base pair (UBP) have recently yielded three promising candidates, one based on alternative hydrogen bonding, and two based on hydrophobic and packing forces. All three of these UBPs are replicated and transcribed with remarkable efficiency and fidelity, and the latter two thus demonstrate that hydrogen bonding is not unique in its ability to underlie the storage and retrieval of genetic information. This Review highlights these recent developments as well as the applications enabled by the UBPs, including the expansion of the evolution process to include new functionality and the creation of semi‐synthetic life that stores increased information. 相似文献
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建立了全自动免疫亲和在线净化/高效液相色谱快速高通量测定饲料中黄曲霉毒素(Aflatoxins,AFT)的分析方法。饲料样品经乙腈-水(80∶20,体积比)提取,3 g/L Triton X-100水溶液10倍稀释后,用自动进样器注入RIDACREST在线固相萃取系统并流经黄曲霉毒素免疫亲和小柱,以甲醇-水(45∶55,体积比)为流动相,流速为1.0 m L/min,C18色谱柱(150 mm×3.5 mm,5μm)分离,光化学衍生,荧光检测器测定。根据3倍信噪比的峰响应值,确定黄曲霉毒素B1,B2,G1,G2的检出限分别为0.08,0.05,0.18,0.08μg/kg,分别在1~100,0.24~24,0.56~56,0.24~24μg/kg范围内呈线性相关,相关系数(r2)分别为0.999 4,0.999 7,0.999 8和0.999 8;AFT在猪饲料、鸡饲料、宠物饲料和饲料原料4类样品中的加标回收率为72.6%~103%,相对标准偏差为2.5%~4.9%。该方法一次装柱可检测60个样品,液相色谱分析一个样品总的运行时间为15 min,所以1 d可检测70~80个样品,满足饲料中黄曲霉毒素快速高通量准确定量检测的需要。 相似文献
74.
全自动在线固相萃取-液相色谱-高分辨质谱法测定麦卢卡蜂蜜中的特征标志物 总被引:1,自引:0,他引:1
建立了全自动在线固相萃取-液相色谱-高分辨质谱(SPE-LC-HRMS)测定麦卢卡蜂蜜中特征标志物3,5-二甲氧基苯甲酸甲酯-4-双葡萄糖糖苷(leptosperin)的方法。以Dikma Diamonsil Plus C_(18)色谱柱(150 mm×4.6 mm,5μm)为分析柱,0.1%(v/v)甲酸水溶液-乙腈为流动相进行梯度洗脱,在电喷雾负离子、目标二级离子扫描模式下进行检测,外标法定量。结果表明,在0.5~100.0 mg/L范围内该分析物的线性关系良好,相关系数为0.999 3,方法的检出限(LOD,S/N≥3)和定量限(LOQ,S/N≥10)分别为3 mg/kg和10 mg/kg。在不同蜂蜜样品中分别添加50.0、100.0、200.0 mg/kg(洋槐蜜中添加10.0、20.0、50.0 mg/kg)特征化合物标准品进行加标回收率试验,平均回收率为82.0%~95.2%,相对标准偏差为2.7%~9.7%(n=6)。利用该方法对来自新西兰12种不同品种的95个蜂巢成熟原蜜和来自4个国家50个商品化蜂蜜进行了验证。该法快速、灵敏、准确,可为解决进口新西兰麦卢卡蜂蜜的判别难题提供技术支持。 相似文献
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Exact controllability of nodal profile for 1‐D first order quasilinear hyperbolic systems with internal controls 下载免费PDF全文
Kaili Zhuang 《Mathematical Methods in the Applied Sciences》2017,40(18):6565-6580
For 1‐D first order quasilinear hyperbolic systems without zero eigenvalues, based on the theory of exact boundary controllability of nodal profile, using an extension method, the exact controllability of nodal profile can be realized in a shorter time by means of additional internal controls acting on suitably small space‐time domains. On the other hand, using a perturbation method, the exact controllability of nodal profile for 1‐D first order quasilinear hyperbolic systems with zero eigenvalues can be realized by additional internal controls to the part of equations corresponding to zero eigenvalues. Furthermore, by adding suitable internal controls to all the equations on suitable domains, the exact controllability of nodal profile for systems with zero eigenvalues can be realized in a shorter time. 相似文献
77.
Exact boundary controllability for 1‐D quasilinear wave equations with dynamical boundary conditions 下载免费PDF全文
Yue Wang Günter Leugering Tatsien Li 《Mathematical Methods in the Applied Sciences》2017,40(10):3808-3820
By equivalently replacing the dynamical boundary condition by a kind of nonlocal boundary conditions, and noting a hidden regularity of solution on the boundary with a dynamical boundary condition, a constructive method with modular structure is used to get the local exact boundary controllability for 1‐D quasilinear wave equations with dynamical boundary conditions. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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Yoko Nunome Kenji Kodama Hyunkook Park Kozo Matsumoto Sang Chun Lee Kuniyuki Kitagawa 《Microchemical Journal》2011,99(2):470-477
A new system combining a soft plasma ionization (SPI) source with a time-of-flight mass spectrometer (TOFMS) has been successfully developed and applied to direct and on-line analysis of nanoparticles in smoke generated during combustion of mosquito coils with no sample preparation. The mass spectra of nanoparticles in smoke were examined in conjunction with the effects of species, pressure and current of the SPI discharge on fragmentation. The results indicated that a maximum mass of m/z 1576 was detectable when the following optima SPI conditions were satisfied: a He gas pressure of 1000 Pa with an air pressure of 1600 Pa and a discharge current of 110 mA. Furthermore, considering the results for emission spectra we suppose an ionization mechanism of SPI in which excitation and ionization of nitrogen molecule is promoted by the presence of He gas, leading to promote the smoke sample ionization. The mass spectrum of nanoparticles showed specific patterns of a peak interval of 74 which were assigned to triacetylene (1,3,5-hexatriyne). The most abundant peak in the mass spectrum, at m/z 452, was assigned to triacontanoic acid. 相似文献